Conservation of connectivity of model-space effective interactions under a class of similarity transformation.

نویسندگان

  • Chang-Kui Duan
  • Yungui Gong
  • Hui-Ning Dong
  • Michael F Reid
چکیده

Effective interaction operators usually act on a restricted model space and give the same energies (for Hamiltonian) and matrix elements (for transition operators, etc.) as those of the original operators between the corresponding true eigenstates. Various types of effective operators are possible. Those well defined effective operators have been shown to be related to each other by similarity transformation. Some of the effective operators have been shown to have connected-diagram expansions. It is shown in this paper that under a class of very general similarity transformations, the connectivity is conserved. The similarity transformation between Hermitian and non-Hermitian Rayleigh-Schrodinger perturbative effective operators is one of such transformations and hence the connectivity can be deducted from each other.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 121 11  شماره 

صفحات  -

تاریخ انتشار 2004